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🧽Structure & grades

Polyurethane foam · The low-λ organic foam of fridges and buildings — excellent insulation, a fire design problem unless PIR and coverings are honest.

At a glance
Score intensity

Darker cells mean a higher score for this topic on that metric.

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Quick answers

Is Polyurethane foam non-combustible?

Declared reaction class in this atlas: typically E–B with facers; not A1. Assemblies still need resistance tests.

Does Polyurethane foam insulate?

Thermal mark 88/100 versus the atlas. Conductivity note: λ ~0.022–0.028 W/m·K (aged PIR boards, bands).

What is the density band?

30–60 kg/m³ rigid boards

How is it made?

Origin story: Otto Bayer 1937; fridge foam 1950s (Germany).

Can it be recycled?

Circularity mark 32/100 — editorial, route-specific.

Typical melting or failure heat?

pyrolyses; does not melt cleanly

heat 36 · fire 28

Start with this section - Structure & grades

What holds Polyurethane foam together is not the nickname. Formula R-NH-COO-R′ network + blowing agent, density 30–60 kg/m³ rigid boards.

Meters are atlas-relative. Grades are the SKUs buyers write.

Phases

R-NH-COO-R′ network + blowing agent

Chemistry

Polyurethane foam is specified as R-NH-COO-R′ network + blowing agent. Density band 30–60 kg/m³ rigid boards.

Microstructure

Order

Processing sets grain, crystallinity or fibre orientation — the reason two lots of Polyurethane foam can test differently.

Interfaces

Surfaces

Coatings, oxide films, sizings or paper faces often decide weather and fire behaviour more than the bulk brochure.

Defects

Flaws

Inclusions, voids, knots, pinholes or residual stress start the failures that mill certificates do not list.

Grades

Variants

Polyurethane foam is a family. Grade names below are the ones buyers actually write on RFQs.

Ageing

Time

Moisture, UV, creep, hydrogen or carbonation shift properties in service. Design to the aged state.

Relative meters

Strength20

Strength is an editorial 0–100 mark relative to the other 31 materials in this atlas — not a laboratory certificate.

Heat envelope36

Heat envelope is an editorial 0–100 mark relative to the other 31 materials in this atlas — not a laboratory certificate.

Fire behaviour28

Fire behaviour is an editorial 0–100 mark relative to the other 31 materials in this atlas — not a laboratory certificate.

Insulation88

Insulation is an editorial 0–100 mark relative to the other 31 materials in this atlas — not a laboratory certificate.

Workability74

Workability is an editorial 0–100 mark relative to the other 31 materials in this atlas — not a laboratory certificate.

Circularity32

Circularity is an editorial 0–100 mark relative to the other 31 materials in this atlas — not a laboratory certificate.

Grades

Flexible slabstock

Furniture, auto.

Furniture, auto.

Rigid PUR

Appliances.

Appliances.

PIR board

Buildings, better fire index.

Buildings, better fire index.

Spray closed-cell

Roofs, rim joists.

Roofs, rim joists.

Elastofoam

Integral skin.

Integral skin.

Bonds

Primary bonding

Polyurethane foam holds together by ionic/covalent networks.

Secondary forces

Hydrogen bonds, van der Waals stacks or grain-boundary cohesion set toughness and moisture uptake.

Composites & fills

Fillers, fibres, plasticisers or aggregates are part of the real product, not impurities.

Environment film

Oxides, chars, sizings or paints are the layer the world actually meets.

Change the grade, the coating or the moisture and you have a different material with the same English name.

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